Examining the role of Rh/Si cooperation in alkene hydrogenation by a pincer-type [P2Si]Rh complex.

نویسندگان

  • Matthew T Whited
  • Alexander M Deetz
  • Theodore M Donnell
  • Daron E Janzen
چکیده

A bis(phosphine)/triflatosilyl pincer-type Rh(i) complex can reversibly store one equivalent of H2 across the Si-Rh bond upon triflate migration from silicon to rhodium. The triflatosilyl complex serves as an effective precatalyst for norbornene hydrogenation, but Si-OTf bond cleavage is not implicated in the major catalytic pathway. The combined findings suggest possible strategies for M/Si cooperation in catalytic processes.

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عنوان ژورنال:
  • Dalton transactions

دوره 45 24  شماره 

صفحات  -

تاریخ انتشار 2016